Approved products for use in the UK's public water supply
A list of the products approved for use in contact with drinking water in the UK.
Annex 2: List of Relevant European Standards
2.1 British Standards BSEN for Chemicals used for Treatment of Water
IMPORTANT NOTES
1. The existence of a relevant EN standard does not necessarily mean that all supplies of a specific treatment chemical or product will have been tested to and shown to meet the appropriate requirements of the EN. These standards contain requirements for impurities and may additionally have a National Condition of Use assigned to them. Since EN standards for drinking water treatment chemicals and products do not contain mandatory requirements for attestation of conformity, it is the responsibility of the user of these products to ensure that the treatment chemicals or products provided by a specific supplier fully meet the test requirements of the relevant EN standard by provision of a certificate of attestation for the batch of chemical supplied or by internally checking through their own laboratories.
2. Clause 6.1.10.2 of BS 6700: 2006 (Design, installation, testing and maintenance of services supplying water for domestic use within buildings and their curtilages - Specification) states that chemicals used for disinfection of drinking water installations shall be those that are listed in the UK's List of substances, products and processes approved under the relevant regulations .
This advice is wrong; products listed in the "List of Approved Products for use in Public Water Supply", the current title of this publication, have not been assessed for their effectiveness in any situation, and their safety has not been considered in the context of building water systems. BSi Standards is currently amending this clause of BS 6700.
For all of the chemicals listed the following general national condition of use applies:
The method of use and the purity of these products shall be such that, in the case of water for public supply, the water so treated meets the requirements of the relevant regulations .
BSEN |
Chemical |
Additional National Conditions of Use |
---|---|---|
13194: 2000 |
Acetic acid |
None |
1302: 1999 |
Aluminium based co-agulants - Analytical methods |
None |
881: 2004 |
Aluminium chloride, aluminium chloride hydroxide and aluminium chloride hydroxide sulfate (monomeric) |
None |
935: 2004 |
Aluminium iron (III) chloride (monomer) and aluminium iron (III) chloride hydroxide (monomeric) |
None |
887: 2004 |
Aluminium iron (III) sulfate |
None |
878: 2004 |
Aluminium sulfate |
None |
12122: 2005 |
Ammonia solution |
None |
12123: 2005 |
Ammonium sulfate |
None |
1421: 2005 |
Ammonium chloride |
None |
1407: 2008 |
Anionic and nonionic polyacrylamides |
(i) no batch must contain more than 0.020% of free acrylamide monomer based on the active ingredient content; (ii) the dose must average no more than 0.25 mg l -1 and never exceed 0.50 mg l -1 of the active ingredient; (iii) an upper limit for the content of free acrylamide monomer must be stated by the supplier for every batch; (iv) the method used for the analysis for free acrylamide monomer is entitled 'Determination of Acrylamide' published in the series 'Methods for the Examination of Waters and Associated Materials' by the Environment Agency. |
1018: 2006 |
Calcium carbonate |
None |
12485: 2001 |
Calcium carbonate, high-calcium lime and half burnt dolomite - Test methods |
None |
900: 2007 |
Calcium hypochlorite |
None |
1204: 2005 |
Calcium tetrahydrogen bis(orthophosphate) |
None |
936: 2006 |
Carbon dioxide |
None |
1410: 2008 |
Cationic polyacrylamides |
(i) no batch must contain more than 0.020% of free acrylamide monomer based on the active ingredient content; (ii) the dose must average no more than 0.25 mg l -1 and never exceed 0.50 mg l -1 of the active ingredient; (iii) an upper limit for the content of free acrylamide monomer must be stated by the supplier for every batch; and (iv) the method used for the analysis for free acrylamide monomer is entitled 'Determination of Acrylamide' published in the series 'Methods for the Examination of Waters and Associated Materials' by the Environment Agency. |
937: 1999 |
Chlorine |
None |
12671: 2000 |
Chlorine dioxide |
The combined concentration of chlorine dioxide, chlorite and chlorate should not exceed 0.5mg l -1 as chlorine dioxide in the water entering supply. |
12386: 2005 |
Copper sulfate |
None |
1202: 2005 |
Dipotassium hydrogen orthophosphate |
None |
1199: 2005 |
Disodium hydrogen orthophosphate |
None |
1205: 2005 |
Disodium dihydrogen pyrophosphate |
None |
13176: 2000 |
Ethanol |
None |
1017: 2008 |
Half-burnt dolomite |
None |
12175: 2006 |
Hexafluorosilicic acid |
None |
12518: 2008 |
High-calcium lime |
None |
939: 2000 |
Hydrochloric acid |
Permission or consent for disposal of any wastewater generated to a sewer or watercourse must be obtained from the relevant water service company or Environment Agency, in England and Wales or Scottish Environment Protection Agency ( SEPA) in Scotland as appropriate. |
902: 2000 |
Hydrogen peroxide |
Permission or consent for disposal of any wastewater generated to a sewer or watercourse must be obtained from the relevant water service company or Environment Agency in England and Wales or Scottish Environment Protection Agency ( SEPA) in Scotland , as appropriate. Products conforming to EN902 shall not contain stabilising or activation agents. If a product contains such agents it requires approval under the relevant regulations . Prior to introduction into supply all residual hydrogen peroxide must be demonstrably removed/destroyed |
888: 2004 |
Iron(III) chloride |
None |
891: 2004 |
Iron(III) chloride sulfate |
None |
15029:2006 |
Iron (III) hydroxide oxide |
Under consideration - please seek advice from DWI |
889: 2004 |
Iron(II) sulfate |
None |
890: 2004 |
Iron(III) sulphate liquid |
None |
14664: 2004 |
Iron(III) sulphate, solid |
None |
12126: 2005 |
Liquefied ammonia |
None |
13177: 2002 |
Methanol |
None |
1406: 1998 |
Modified starches |
The dose must not exceed 5 mg l -1 of active ingredient. |
1204: 2005 |
Monocalcium phosphate |
None |
1201: 2005 |
Monopotassium hydrogen orthophosphate |
None |
1197: 2006 |
Monozinc phosphate solution |
None |
12876: 2000 |
Oxygen |
None |
1278: 1999 |
Ozone |
None |
974: 2003 |
Phosphoric acid |
Permission or consent for disposal of any wastewater generated to a sewer or watercourse must be obtained from the relevant water service company or Environment Agency in England and Wales or Scottish Environment Protection Agency ( SEPA) in Scotland, as appropriate. |
15040:2006 |
Phosphonic acids and salts |
Under consideration - please seek advice from DWI |
1408: 2008 |
Poly(diallyldimethylammonium chloride) |
The dose used must not exceed 10 mg l -1 of active ingredient. |
883: 2004 |
Polyaluminium chloride hydroxide and polyaluminium chloride hydroxide sulfate |
None |
885: 2004 |
Polyaluminium chloride hydroxide silicate |
None |
886: 2004 |
Polyaluminium hydroxide silicate sulfate |
None |
1409: 2008 |
Polyamines |
(i) The average dose should be 2.5 mg l -1 and never exceed 5 mg l -1 of active ingredient; (ii) no batch must contain more than 40 mg of 3-monochloropropane 1,2-diol per kg of active ingredient; (iii) the analytical system used for determining the batch content must have a limit of detection no greater than 4 mg kg -1 and a maximum total standard deviation no greater than 4 mg kg -1 at 40 mg kg -1. Both estimates must have at least 10 degrees of freedom and have been determined from batches of analyses carried out on not less than five separate days; and (iv) the supplier must state for every batch an upper limit for the content of 3-monochloropropane 1,2-diol. |
15039:2006 |
Polycarboxylic acids and salts |
Under consideration - please seek advice from DWI |
15041:2006 |
Polyphosphates |
Under consideration - please seek advice from DWI |
1201: 2005 |
Potassium dihydrogen orthophosphate |
None |
12672: 2000 |
Potassium permanganate |
None |
12678: 2000 |
Potassium peroxomonosulfate |
None |
1211: 2005 |
Potassium tripolyphosphate |
None |
15030:2006 |
Silver salts |
On advice from HSE - these compounds may not be used in contact with water intended for human consumption. |
1205: 2005 |
Sodium acid pyrophosphate |
None |
1405: 1998 |
Sodium alginate |
the dose used must not exceed 0.5 mg l -1 of active ingredient |
882: 2004 |
Sodium aluminate |
None |
1208: 2005 |
Sodium calcium polyphosphate |
None |
897: 2005 |
Sodium carbonate |
None |
15028:2006 |
Sodium chlorate |
Under consideration - please seek advice from DWI |
14805:2008 |
Sodium chloride for OSEC |
Under consideration - please seek advice from DWI |
973: 2002 |
Sodium chloride for regeneration of ion exchangers |
None |
938: 2000 |
Sodium chlorite |
(i) the dose must be such that the combined concentration of chlorine dioxide, chlorite and chlorate does not exceed 0.5 mg l -1 as chlorine dioxide in water potentially entering supply; and (ii) permission or consent for disposal of any wastewater generated to a sewer or water course must be obtained from the relevant water service company or Environment Agency in England and Wales or Scottish Environment Protection Agency ( SEPA) in Scotland, as appropriate. |
12931: 2000 12932: 2000 12933: 2000 |
Sodium dichloroisocyanurate, anhydrous Sodium dichloroisocyanurate, dihydrate Trichloroisocyanuric acid |
Conditions if product is used as a cleaning agent: (i) the dose must be such that the final concentration in the water used to wash installations does not exceed 1000 mg l -1 of free available chlorine; (ii) that following cleaning and disinfection, the installation is flushed to ensure that the residual chlorine concentration is acceptable to consumers; and (iii) permission or consent for disposal of any wastewater generated to a sewer or watercourse must be obtained from the relevant water service company or Environment Agency in England and Wales or Scottish Environment Protection Agency ( SEPA) in Scotland, as appropriate. Water companies should check with their suppliers to ensure that products to be cleaned and disinfected will not be adversely affected by the concentration of chlorine to be employed. Conditions if product is used as an emergency disinfectant: (i) where circumstances are such that the water being treated is not grossly contaminated and a controlled contact time of not less than 15 minutes between dosing and taking it into use can be maintained, not more than 10 mg l -1 of sodium dichloro-isocyanurate compound should be applied and not more than 1mg l -1 of free residual chlorine should be present at the end of the relevant contact time. It is recommended that consumers should be exposed to such waters containing chloro-isocyanurates for only as long as is required to restore conventional treatment, or for no more than 90 days in any period of a year, whichever is applicable; (ii) under circumstances where water sources may be grossly contaminated, to ensure inactivation of most likely harmful organisms, up to 20 mg l -1 sodium dichloro-isocyanurate may be added, with a recommended contact time of 15 minutes before use. It is recommended that consumption of water dosed at this rate of treatment should be for only as long as is necessary before it is possible to effect control of the residual chlorine after contact to 1 mg l -1, and then to follow the requirements set out in condition (i); and (iii) should it be necessary for specific groups of consumers to be exposed to water containing chloro-isocyanurates for periods greater than 90 days either continuously or in a year, it is recommended that independent medical advice be obtained from a person who is not under the control of the water undertaker. |
1198: 2005 |
Sodium dihydrogen orthophosphate |
None |
12121: 2005 |
Sodium disulfite |
None |
12173: 2005 |
Sodium fluoride |
None |
12174: 2006 |
Sodium hexafluorosilicate |
None |
898: 2005 |
Sodium hydrogen carbonate |
None |
12120: 2005 |
Sodium hydrogen sulfite |
None |
896: 2005 |
Sodium hydroxide |
None |
901: 2007 |
Sodium hypochlorite |
The method of use and the purity of these products shall be such that, in the case of water for public supply, the water so treated meets the requirements of the relevant regulations . |
15482:2007 |
Sodium Permanganate |
Under consideration - please seek advice from DWI |
12926: 2000 |
Sodium peroxodisulfate |
None |
1212: 2005 |
Sodium polyphosphate |
None |
1209: 2003 |
Sodium silicate |
None |
12124: 2005 |
Sodium Sulfite |
None |
12125: 2005 |
Sodium thiosulfate |
None |
1210: 2005 |
Sodium tripolyphosphate |
None |
1019: 2005 |
Sulfur dioxide |
None |
899: 2003 |
Sulfuric acid |
None |
1207: 2005 |
Tetrapotassium pyrophosphate |
None |
1206: 2005 |
Tetrasodium pyrophosphate |
None |
1203: 2005 |
Tripotassium orthophosphate |
None |
1200: 2005 |
Trisodium orthophosphate |
None |
2.2 British Standards BSEN for Inorganic Supporting and Filtering Materials Used for Treatment of Water Intended for Human Consumption
For all of the products listed the following general national condition of use applies;
The method of use and the purity of these products shall be such that, in the case of water for public supply, the water so treated meets the requirements of the relevant regulations .
BSEN |
Title |
Additional National Conditions of Use |
---|---|---|
12909: 2005 |
Anthracite |
None |
12912: 2005 |
Barite |
None |
13754: 2003 |
Bentonite |
None |
14456: 2004 |
Bone charcoal |
The contact bed containing the product must be adequately back-washed (until backwash water is clear of fines) to remove any readily leachable materials before connection to the supply. |
12905: 2005 |
Expanded aluminosilicate |
None |
12910: 2005 |
Garnet |
None |
13753: 2002 12915 - 1: 2003 12915 - 2: 2003 12907: 2003 |
Granular activated alumina Granular activated carbon. Part 1: Virgin GAC Granular activated carbon. Part 2: Reactivated GAC Pyrolised coal material |
(i) the contact bed containing the product must be adequately back-washed (until backwash water is clear of fines) to remove any readily leachable materials before connection to the supply; and (ii) before connection to the supply, the water undertaker or their appointed agent must carry out tests on the filtrate water to establish that use of the contact bed will not cause any adverse effect on the quality of water to be put into supply. These tests must include measurement of chlorine demand and a qualitative odour assessment, as well as tests to confirm that leaching of activating agents or any other substance used in the preparation or regeneration of the product will not cause a contravention of the standards prescribed in the relevant regulations . |
12901: 1999 |
Inorganic supporting and filtering materials - Definitions |
None |
12902: 2004 |
Inorganic supporting and filtering materials - Methods of test |
None |
14369: 2003 |
Iron-coated granular activated alumina |
None |
13752: 2003 |
Manganese dioxide |
None |
12911: 2006 |
Manganese greensand |
None |
12903: 2003 |
Powered activated carbon |
The dose must not exceed 100 mg l -1. |
12913: 2005 |
Powdered diatomaceous earth |
None |
12914: 2005 |
Powdered perlite |
None |
12906: 2005 |
Pumice |
None |
12904: 2005 |
Silica sand and silica gravel |
None |
2.3 British Standards BSEN on the Influence of Materials on Water Intended for Human Consumption
BSEN |
Title |
---|---|
1420-1: 1999 |
Influence of organic materials on water intended for human consumption - Determination of odour and flavour assessment of water in piping systems |
12873-1: 2003 |
Influence of materials on water intended for human consumption - Influence due to migration - Part 1: Test method for non-metallic and non-cementitious factory made products |
12873-2: 2005 |
Influence of materials on water intended for human consumption - Influence due to migration - Part 2: Test method for non-metallic and non-cementitious site - applied materials |
12873-3: 2006 |
Influence of materials on water intended for human consumption - Influence due to migration - Part 3: Test method for ion exchange and adsorbent resins |
12873-4: 2006 |
Influence of materials on water intended for human consumption - Influence due to migration - Part 4: Test method for water treatment membranes |
13052-1: 2001 |
Influence of materials on water intended for human consumption - Organic materials - Determination of colour and turbidity of water in piping systems - Part 1: Test method |
14395-1: 2004 |
Influence of materials on water intended for human consumption - Organoleptic assessment of water in storage systems - Part 1: Test method |
14718: 2006 |
Influence of organic materials on water intended for human consumption - Determination of the chlorine demand - Test Method |
14944-1: 2006 |
Influence of factory made cementitious products on organoleptic parameters - Test methods - Part 1: Influence of factory made cementitious products on organoleptic parameters |
14944-3: 2007 |
Influence of factory made cementitious products on organoleptic parameters - Test methods - Part 3: Migration of substances from factory-made cementitious products |
15664: 2008 |
Influence of metallic materials on water intended for human consumption - Dynamic rig test for assessment of metal release - Part 1: Design and operation |
2.4 List of Authorised Cement Admixture Components
Regulation 25/31 letters 6/2000 and 03/2003 in England and Wales and Regulation 25 letters 3/2001 and 4/2003 in Scotland gave details of the arrangements for authorisation of civil engineering use of concrete in water retaining structures in treatment and distribution systems. The following list gives the chemical identity of admixture components considered acceptable for use in cement admixtures for use in concrete in contact with water in water retaining structures, providing the admixture is not added to the concrete at a concentration exceeding the manufacturer's recommended dose.
Admixture component |
Used as |
---|---|
Abietic acid salts |
Air entrainer |
Aluminates, sodium or potassium |
Accelerator |
Aluminium hydroxides, amorphic |
Accelerator |
Anionic surfactants |
Air entrainer |
Butyl stearate |
Waterproofer/ water repellent |
Carbonate, sodium or potassium |
Accelerator |
Cellulose ethers |
Stabiliser/pumping aid |
Citric acid |
Retarder |
Decanoate, sodium |
Air entrainer |
Dimethylsiloxane, poly- |
Defoamer agent for plasticisers/ superplasticisers |
Dodecyl benzene sulphonate, sodium |
Air entrainer |
Fatty acid soaps |
Waterproofer/ water repellent |
Formate, calcium |
Accelerator |
Gluconic and Heptonic acid salts |
Retarder/ water reducer/ plasticiser |
Lauryl ether sulphate, sodium |
Air entrainer |
Lignosulphonates |
Water reducer/ plasticiser |
Mono and di saccharides, eg sucrose, xylose |
Retarder |
Nitrate, calcium, sodium or potassium |
Accelerator |
Oleic acid and salts |
Waterproofer/ water repellent |
Oxalate, lithium |
Accelerator |
Polysaccharides |
Water reducer/ plasticiser |
Phosphate, dibutyl |
Defoamer agent for plasticisers/ superplasticisers |
Phosphate, tributyl |
Defoamer agent for plasticisers/ superplasticisers |
Phosphates (inorganic) |
Retarder |
Phosphonates (organic) |
Retarder |
Polycarboxylate/ polyether copolymer |
Superplasticiser |
Silicates, sodium |
Accelerator |
Starch ethers |
Stabiliser/pumping aid |
Stearate salts |
Waterproofer/ water repellent |
Sulphonated melamine formaldehyde condensate |
Superplasticiser |
Sulphonated naphthalene formaldehyde condensate |
Superplasticiser |
Tartaric acid |
Retarder |
Thiocyanate, sodium |
Accelerator |
Triethanolamine |
Water reducer/ plasticiser |
Note 1:Biocides/ preservative and agents, antifoam/ air control agents, present in the admixture at less than 1.0% in total and the dilution water used in cement admixture formulations are excluded from the requirement for authorisation.
Note 2: The use of ferrous or stannous sulphate is acceptable as reducing agents to control concentrations of hexavalent chromium (VI) in cement.
Note 3: Fibre additions to concrete - , the use of polymeric or carbon reinforcing fibres should not be a cause for concern, providing that either -
a. concrete made with them, at the proposed concentration/level conforms with the requirements of BS 6920 odour and flavour and growth of aquatic microorganisms tests OR
b. the reinforcing fibres have already met the requirements of BS 6920
Contact
Email: Central Enquiries Unit ceu@gov.scot
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